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JEE MainChemistryChemical Bonding and Molecular Structure

Consider the following chemical species: I ₃^-, SF ₄, XeF ₄ , and BrF ₃ . Identify the species that possesses the maximum number of lone pairs of electrons on its central atom. What is the hybridization and molecular geometry of this species?

Options

  1. Asp^3d^2 , Square planar
  2. Bsp^3d , T-shaped
  3. Csp^3d , Linear
  4. Dsp^3d , See-saw

Correct answer

C. sp^3d , Linear

Step-by-step solution

First, determine the number of lone pairs on the central atom for each species. 1. I ₃^- : The central I atom has 7 valence electrons. Adding 1 electron for the negative charge gives 8 electrons. It forms 2 single bonds with the other two iodine atoms. Number of lone pairs = 8 - 2 2 = 3 . 2. SF ₄ : Central S atom has 6 valence electrons. It forms 4 single bonds. Number of lone pairs = 6 - 4 2 = 1 . 3. XeF ₄ : Central Xe atom has 8 valence electrons. It forms 4 single bonds. Number of lone pairs = 8 - 4 2 = 2 . 4. B

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