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JEE MainChemistryChemical Bonding and Molecular Structure

Which of the following pairs of molecules has a net zero dipole moment for both of its members?

Options

  1. ACO ₂, SO ₂
  2. BXeF ₄, SF ₆
  3. CBF ₃, NH ₃
  4. DH ₂ O , H ₂ S

Correct answer

B. XeF ₄, SF ₆

Step-by-step solution

The net dipole moment of a molecule is the vector sum of all its bond dipoles and lone pair dipoles. For CO ₂ (linear), the dipole moment is zero. However, SO ₂ has a bent structure due to one lone pair on sulfur, resulting in a non-zero dipole moment. For BF ₃ (trigonal planar), the dipole moment is zero. NH ₃ has a trigonal pyramidal structure with one lone pair, giving it a non-zero dipole moment. For H ₂ O and H ₂ S , both have bent structures with two lone pairs on the central atom, so both have non-zero dipol

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