JEE MainChemistryp Block Elements (Group 15, 16, 17 & 18)
An element M of Group 15 has a maximum covalency of four due to the absence of d-orbitals in its valence shell, but it can form strong p - p multiple bonds with oxygen. Which of the following is a direct consequence of these properties?
Options
- AM forms oxides in +5 oxidation state but does not form pentahalides.
- BM forms pentahalides but does not form oxides in +5 oxidation state.
- CM cannot exhibit an oxidation state of +5 in any of its compounds.
- DM forms both pentahalides and oxides in +5 oxidation state.
Correct answer
A. M forms oxides in +5 oxidation state but does not form pentahalides.
Step-by-step solution
The element M described is nitrogen. Because nitrogen lacks d-orbitals in its valence shell, its maximum covalency is restricted to 4. Therefore, it cannot accommodate five halogen atoms to form pentahalides (e.g., NCl ₅ does not exist). However, nitrogen can form strong p - p multiple bonds with oxygen. In oxides like N ₂ O ₅ , nitrogen achieves a +5 oxidation state while maintaining a covalency of 4 (through a combination of single, double, and coordinate bonds). Thus, it forms oxides in the +5 oxidation state bu