JEE MainChemistryp Block Elements (Group 15, 16, 17 & 18)
Consider the following unbalanced chemical equations representing the reactions involving halogens ( X, Y, Z ): (i) Y₂ + H₂O H^+ + Y^- + O₂ (ii) X₂ + H₂O HX + HOX (iii) Z^- + H^+ + O₂ Z₂ + H₂O Identify the halogens X, Y , and Z respectively.
Options
- AX = F , Y = Cl , Z = I
- BX = Cl , Y = I , Z = F
- CX = Cl , Y = F , Z = I
- DX = I , Y = F , Z = Br
Correct answer
C. X = Cl , Y = F , Z = I
Step-by-step solution
Reaction (i) shows the oxidation of water to oxygen by a halogen. Among halogens, only fluorine ( F₂ ) oxidises water to oxygen. Thus, Y is F . Reaction (ii) shows the disproportionation of a halogen in water to form hydrohalic and hypohalous acids. Chlorine ( Cl₂ ) and bromine ( Br₂ ) undergo this reaction. Thus, X can be Cl or Br . Reaction (iii) shows the oxidation of a halide ion by oxygen in an acidic medium. The reaction of iodine with water is non-spontaneous, but the reverse reaction occurs, i.e., iodide io