Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryThermodynamics (C)

For a certain thermodynamic process involving an ideal gas, the following parameters are observed: U 0, q = 0 , and w 0 . Which of the following physical processes corresponds to these conditions?

Options

  1. AAdiabatic expansion of an ideal gas against a non-zero external pressure
  2. BAdiabatic compression of an ideal gas
  3. CFree expansion of an ideal gas in an insulated container
  4. DIsothermal expansion of an ideal gas

Correct answer

A. Adiabatic expansion of an ideal gas against a non-zero external pressure

Step-by-step solution

The condition q = 0 implies that the process is adiabatic (no heat exchange with the surroundings). The condition w 0 (using IUPAC chemistry sign convention) indicates that work is done by the system, which corresponds to an expansion process against a non-zero external pressure. Applying the First Law of Thermodynamics: U = q + w Since q = 0 and w 0 , we get U 0 , which is consistent with the given conditions. Therefore, the process is an adiabatic expansion of an ideal gas against a non-zero external pressure. An

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant temperature of 600 K in two steps: first, against a constant external pressure of P bar ( 2 < P < 2026List-I contains various physical/chemical processes, and List-II contains combinations of changes in enthalpy ( H ) and entropy ( S ). Match each entry in List-I to the appropriate 2026Consider the reaction 2 H ₂ S (g) + 3 O ₂(g) 2 H ₂ O (l) + 2 SO ₂(g) The magnitude of enthalpy change for the reaction in kJ mol ⁻¹ is ________. (Nearest integer) Given: _fH^ ( H ₂ 2026Match List - I with List - II. Given V₁ and V₂ are initial and final volumes respectively. List - I (Isothermal process) List - II (Expression) A. Reversible expansion I. q = 0 B. 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V ) involved between states 1 and 2 . A. Expansion in single stage w_A B. Expansion in multi 2026Consider the reaction X Y at 300 K. If H^ and K are 28.40 kJ mol ⁻¹ and 1.8 10⁻⁷ at the same temperature, then the magnitude of S^ for the reaction in J K ⁻¹ mol ⁻¹ is _______. (Ne 2026Consider the following data for the reaction X₂(g) + Y₂(g) 2XY(g) at 600 K . The _r G^ (in kJ mol ⁻¹ ) for the reaction is : Compound _f H^ _ 600K (kJ mol ⁻¹ ) S^ _ 600K (J mol ⁻¹ 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : 2026 Full Thermodynamics (C) list All JEE Main PYQs