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JEE MainChemistryp Block Elements (Group 15, 16, 17 & 18)

Species X is a Group 15 trihalide which cannot act as a Lewis acid because its central atom cannot expand its octet. Species Y is a Group 15 pentahalide that acts as a very powerful oxidizing agent due to the high instability of the +5 oxidation state of its central atom. Identify Species X and Species Y respectively from the given options.

Options

  1. APCl₃ and SbF₅
  2. BNCl₃ and PF₅
  3. CNCl₃ and BiF₅
  4. DPCl₃ and BiF₅

Correct answer

C. NCl₃ and BiF₅

Step-by-step solution

Species X is a Group 15 trihalide that cannot act as a Lewis acid. A Lewis acid must be able to accept an electron pair. Nitrogen trihalides (like NCl₃ ) cannot accept an electron pair because the central nitrogen atom belongs to the second period and lacks vacant d-orbitals to expand its octet. Heavier trihalides like PCl₃ have vacant d-orbitals and can act as Lewis acids by expanding their octet. Thus, Species X is NCl₃ . Species Y is a Group 15 pentahalide that acts as a powerful oxidizing agent. Down Group 15,

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