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JEE MainChemistryChemical Bonding and Molecular Structure

Consider the following list of chemical species: XeF ₂, I ₃⁻, PCl ₅, SF ₄, BrF ₃, XeF ₄, ClF ₅ Find the sum of the number of lone pairs present on the central atoms of ONLY those species from the list that possess sp ^3 d hybridization.

Options

  1. A12
  2. B6
  3. C9
  4. D5

Correct answer

C. 9

Step-by-step solution

First, determine the hybridization and the number of lone pairs on the central atom for each species. For XeF ₂ : Xe has 8 valence electrons. It forms 2 bonds and has 3 lone pairs. Steric number = 5 ( sp ^3 d ). For I ₃⁻ : Central I has 7 valence electrons + 1 (charge) = 8. It forms 2 bonds and has 3 lone pairs. Steric number = 5 ( sp ^3 d ). For PCl ₅ : P has 5 valence electrons. It forms 5 bonds and has 0 lone pairs. Steric number = 5 ( sp ^3 d ). For SF ₄ : S has 6 valence electrons. It forms 4 bonds and has 1 l

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