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JEE MainChemistryChemical Bonding and Molecular Structure

Consider the species NO ₃⁻ , CO ₃²⁻ and BO ₃³⁻ . Choose the correct option with respect to these three species:

Options

  1. AOnly two are isoelectronic and all have trigonal planar structures
  2. BThey are isoelectronic and only two have trigonal planar structures
  3. CThey are isoelectronic and all have trigonal planar structures
  4. DOnly two are isoelectronic and only two have trigonal planar structures

Correct answer

C. They are isoelectronic and all have trigonal planar structures

Step-by-step solution

Total number of electrons in NO ₃⁻ = 7 + 3 8 + 1 = 32 Total number of electrons in CO ₃²⁻ = 6 + 3 8 + 2 = 32 Total number of electrons in BO ₃³⁻ = 5 + 3 8 + 3 = 32 All three species have 32 electrons, so they are isoelectronic. For the central atom in each species, the steric number is 1 2 (V + M - C + A) . For N in NO ₃⁻ : 1 2 (5 + 0 - 0 + 1) = 3 (sp ^2 hybridized, 0 lone pairs) For C in CO ₃²⁻ : 1 2 (4 + 0 - 0 + 2) = 3 (sp ^2 hybridized, 0 lone pairs) For B in BO ₃³⁻ : 1 2 (3 + 0 - 0 + 3) = 3 (sp ^2 hybridized, 0

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