Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryp Block Elements (Group 15, 16, 17 & 18)

Iodine reacts with an excess of fluorine to form an interhalogen compound A . Complete hydrolysis of compound A yields an oxoacid B along with hydrogen fluoride. The geometry of the anion derived from the oxoacid B is

Options

  1. ATetrahedral
  2. BOctahedral
  3. CSquare planar
  4. DTrigonal pyramidal

Correct answer

A. Tetrahedral

Step-by-step solution

Iodine reacts with excess of fluorine to form iodine heptafluoride ( IF ₇ ). I ₂ + 7 F ₂ (excess) 2 IF ₇ Complete hydrolysis of IF ₇ yields periodic acid ( HIO ₄ ) and hydrogen fluoride. IF ₇ + 4 H ₂ O HIO ₄ + 7 HF The oxoacid B is HIO ₄ , and its anion is the periodate ion, IO ₄^- . In IO ₄^- , the central iodine atom is bonded to four oxygen atoms via sigma and pi bonds, with no lone pairs on the iodine atom. The steric number is 4 , which corresponds to sp^3 hybridization. Thus, the geometry of the IO ₄^- ion is

Practice p Block Elements (Group 15, 16, 17 & 18) on Quantrex Academy →

More from p Block Elements (Group 15, 16, 17 & 18)

Correct statement(s) about the compounds X , Y and Z is(are) 2026Correct statement(s) about the compounds P , Q and R is(are) 2026Find the correct statements related to group 15 hydrides. A. Reducing nature increases from NH₃ to BiH₃ B. Tendency to donate lone pair of electrons decreases from NH₃ to BiH₃ C. T 2026Treatment of a gas ' X ' with a freshly prepared ferrous sulphate solution gives a compound ' Y ' as a brown ring. The compounds X and Y are. 2026Correct statements from the following are: A. Nitrogen in oxidation states from +1 to +4 disproportionates in acid medium. B. Nitrogen has the ability to form d - p multiple bonds 2026Given below are two statements: Statement I: The covalency of oxygen is generally two but it can exceed upto four. The oxidation state of oxygen in SO₂ is -2 and in OF₂ it is +2 . 2026Given below are two statements : Statement (I) : Oxidising power of halogens decreases in the order F₂ > Cl₂ > Br₂ > I₂ , which is the basis of "Layer test". Statement (II) : "Laye 2026Given below are two statements : Statement I : The increasing order of boiling point of hydrogen halides is HCl Statement II : The increasing order of melting point of hydrogen hal 2026 Full p Block Elements (Group 15, 16, 17 & 18) list All JEE Main PYQs