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JEE MainChemistryChemical Bonding and Molecular Structure

Among the following molecules, which one has a non-zero dipole moment?

Options

  1. AXeF ₄
  2. BPCl ₅
  3. CSF ₄
  4. DSF ₆

Correct answer

C. SF ₄

Step-by-step solution

The dipole moment of a molecule depends on its geometry and the vector sum of individual bond dipoles and lone pair dipoles. In XeF ₄ , the central xenon atom has 4 bond pairs and 2 lone pairs. Its geometry is square planar, which is highly symmetrical. The bond dipoles and lone pair dipoles cancel each other out, resulting in a net dipole moment of zero. In PCl ₅ , the central phosphorus atom has 5 bond pairs and 0 lone pairs. Its geometry is trigonal bipyramidal. The three equatorial P-Cl bond dipoles cancel each

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