JEE MainChemistryChemical Bonding and Molecular Structure
Among the following species, the one which is known to exist is:
Options
- A[ PCl ₆]⁻
- B[ SiCl ₆]²⁻
- CNCl ₅
- DPbI ₄
Correct answer
A. [ PCl ₆]⁻
Step-by-step solution
Let us analyze the existence of each species: [ SiCl ₆]²⁻ does not exist because six large chloride ions cannot be accommodated around a relatively small silicon atom due to severe steric hindrance. Also, the interaction between lone pairs of chloride ions and silicon is not very strong. NCl ₅ does not exist because nitrogen belongs to the second period and lacks vacant d-orbitals in its valence shell, restricting its maximum covalency to 4. PbI ₄ does not exist because the Pb-I bond initially formed does not relea