Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryThermodynamics (C)

An ideal gas is enclosed in a cylinder fitted with a frictionless piston and perfectly heat-conducting walls. The cylinder is immersed in a large constant-temperature water bath. The gas is then slowly compressed by gradually adding weights to the piston. Which of the following sets of thermodynamic parameters correctly describes this process?

Options

  1. AU 0, q = 0, w 0
  2. BU = 0, q 0, w 0
  3. CU 0, q 0, w 0
  4. DU = 0, q 0, w 0

Correct answer

D. U = 0, q 0, w 0

Step-by-step solution

The cylinder has perfectly heat-conducting walls and is placed in a constant-temperature bath, and the process is slow. This ensures the process is isothermal. For an ideal gas undergoing an isothermal process, the change in internal energy is zero ( U = 0 ). The gas is being compressed by external weights, which means work is done on the system. According to IUPAC sign convention, work done on the system is positive ( w 0 ). Applying the First Law of Thermodynamics: U = q + w 0 = q + w q = - w Since w 0 , it follo

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant temperature of 600 K in two steps: first, against a constant external pressure of P bar ( 2 < P < 2026List-I contains various physical/chemical processes, and List-II contains combinations of changes in enthalpy ( H ) and entropy ( S ). Match each entry in List-I to the appropriate 2026Consider the reaction 2 H ₂ S (g) + 3 O ₂(g) 2 H ₂ O (l) + 2 SO ₂(g) The magnitude of enthalpy change for the reaction in kJ mol ⁻¹ is ________. (Nearest integer) Given: _fH^ ( H ₂ 2026Match List - I with List - II. Given V₁ and V₂ are initial and final volumes respectively. List - I (Isothermal process) List - II (Expression) A. Reversible expansion I. q = 0 B. 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V ) involved between states 1 and 2 . A. Expansion in single stage w_A B. Expansion in multi 2026Consider the reaction X Y at 300 K. If H^ and K are 28.40 kJ mol ⁻¹ and 1.8 10⁻⁷ at the same temperature, then the magnitude of S^ for the reaction in J K ⁻¹ mol ⁻¹ is _______. (Ne 2026Consider the following data for the reaction X₂(g) + Y₂(g) 2XY(g) at 600 K . The _r G^ (in kJ mol ⁻¹ ) for the reaction is : Compound _f H^ _ 600K (kJ mol ⁻¹ ) S^ _ 600K (J mol ⁻¹ 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : 2026 Full Thermodynamics (C) list All JEE Main PYQs