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MHT CET 202623 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
23 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

MHT CET 2026 · 23 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

Butan-2-ol is heated with red phosphorous and bromine. Find the...

Butan-2-ol is heated with red phosphorous and bromine. Find the number of optical isomers of the product formed.

Options

  1. AZero
  2. BOne
  3. CTwo
  4. DThree

Correct answer

C. Two

Step-by-step solution

The reaction of butan-2-ol with red phosphorus and bromine yields 2-bromobutane.

CH3−CH(OH)−CH2−CH3→P/Br2CH3−CH(Br)−CH2−CH3CH_3-CH(OH)-CH_2-CH_3 \xrightarrow{P/Br_2} CH_3-CH(Br)-CH_2-CH_3

The product, 2-bromobutane, contains exactly one chiral carbon atom (the second carbon is attached to four different groups: −H-H, −Br-Br, −CH3-CH_3, and −CH2CH3-CH_2CH_3).

The number of optical isomers for a compound with nn dissimilar chiral centers is given by 2n2^n.

For n=1n = 1, the number of optical isomers is 21=22^1 = 2. These correspond to the (R) and (S) enantiomers.

Answer: Two
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