MHT CET Medical202622 April 2026Morning ShiftChemistryAlcohols Phenols and EthersActual
Identify the substrate 'S' in the following reaction.
Options
- Ap-Nitrochlorobenzene
- Bo-Nitorchlorobenzene
- C2, 4, 6 - trichloronitrobenzene
- D2, 4, 6 - trinitrochlorobenzene
Correct answer
D. 2, 4, 6 - trinitrochlorobenzene
Step-by-step solution
The given reaction is a nucleophilic aromatic substitution where a leaving group on the benzene ring is replaced by an - OH group from water to form 2,4,6-trinitrophenol (picric acid). Aryl halides are generally unreactive towards nucleophilic substitution. However, the presence of strong electron-withdrawing groups (like - NO ₂ ) at the ortho and para positions with respect to the halogen atom greatly increases their reactivity. In 2,4,6-trinitrochlorobenzene, there are three - NO ₂ groups at the ortho and para po