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MHT CET Medical202622 April 2026Morning ShiftChemistryAlcohols Phenols and EthersActual

Identify the substrate 'S' in the following reaction.

Options

  1. Ap-Nitrochlorobenzene
  2. Bo-Nitorchlorobenzene
  3. C2, 4, 6 - trichloronitrobenzene
  4. D2, 4, 6 - trinitrochlorobenzene

Correct answer

D. 2, 4, 6 - trinitrochlorobenzene

Step-by-step solution

The given reaction is a nucleophilic aromatic substitution where a leaving group on the benzene ring is replaced by an - OH group from water to form 2,4,6-trinitrophenol (picric acid). Aryl halides are generally unreactive towards nucleophilic substitution. However, the presence of strong electron-withdrawing groups (like - NO ₂ ) at the ortho and para positions with respect to the halogen atom greatly increases their reactivity. In 2,4,6-trinitrochlorobenzene, there are three - NO ₂ groups at the ortho and para po

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