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MHT CET 202623 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
23 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

MHT CET 2026 · 23 April · Morning Shift · Chemistry · Aldehydes and Ketones

Benzaldehyde is converted to benzyl alcohol by

Benzaldehyde is converted to benzyl alcohol by

Options

  1. AWurtz reaction
  2. BFittig reaction
  3. CWurtz Fittig reaction
  4. DCannizzaro's reaction

Correct answer

D. Cannizzaro's reaction

Step-by-step solution

Benzaldehyde (C_6H_5CHO)isanaldehydethatdoesnotcontainanyα) is an aldehyde that does not contain any \alpha-hydrogen atom.

When treated with a concentrated alkali solution, it undergoes a disproportionation reaction (self-oxidation and self-reduction) to form one molecule of benzyl alcohol (C_6H_5CH_2OH)andonemoleculeofasaltofbenzoicacid(C6H5COO−) and one molecule of a salt of benzoic acid (C_6H_5COO^-).

This reaction is known as Cannizzaro's reaction.

2C6H5CHO+NaOH→C6H5CH2OH+C6H5COONa2C_6H_5CHO + NaOH \rightarrow C_6H_5CH_2OH + C_6H_5COONa

Wurtz, Fittig, and Wurtz-Fittig reactions are coupling reactions involving alkyl and/or aryl halides in the presence of sodium metal.

Answer: Cannizzaro's reaction
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