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MHT CET 202624 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
24 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

MHT CET 2026 · 24 April · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Which one of the following is NOT an example of an expanded octate?

Which one of the following is NOT an example of an expanded octate?

Options

  1. APCl5\text{PCl}_5
  2. BH2SO4\text{H}_2\text{SO}_4
  3. CSF6\text{SF}_6
  4. DCH4\text{CH}_4

Correct answer

D. CH4\text{CH}_4

Step-by-step solution

In PCl5\text{PCl}_5, the central atom phosphorus forms 55 single bonds, having 1010 valence electrons around it, which is an expanded octet.

In H2SO4\text{H}_2\text{SO}_4, the central atom sulfur forms 66 bonds (22 double bonds and 22 single bonds), having 1212 valence electrons around it, which is an expanded octet.

In SF6\text{SF}_6, the central atom sulfur forms 66 single bonds, having 1212 valence electrons around it, which is an expanded octet.

In CH4\text{CH}_4, the central atom carbon forms 44 single bonds, having exactly 88 valence electrons around it. Carbon belongs to the second period and lacks vacant d-orbitals, so it cannot expand its octet.

Thus, CH4\text{CH}_4 is not an example of an expanded octet.

Answer: CH4\text{CH}_4
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