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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Coordination Compounds

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Coordination Compounds

[Ti(H_2O)_6]^ 2+ is a colored compound where as [Zn(H_2O)_6]^ 2+ is...

[Ti(H2O)6]2+[\text{Ti(H}_2\text{O)}_6]^{2+} is a colored compound where as [Zn(H2O)6]2+[\text{Zn(H}_2\text{O)}_6]^{2+} is colorless, because

Options

  1. ATitanium has completely filled 3d orbitals and Zinc has partially filled 3d orbitals.
  2. BZinc has completely filled 3d orbitals and Titanium has partially filled 3d orbitals.
  3. CZinc has completely filled 4d orbitals.
  4. DTitanium has completely filled 4d orbitals.

Correct answer

B. Zinc has completely filled 3d orbitals and Titanium has partially filled 3d orbitals.

Step-by-step solution

The atomic number of Titanium (Ti) is 2222. Its ground state electronic configuration is [Ar]3d24s2[\text{Ar}] 3d^{2} 4s^{2}.

In the complex [Ti(H2O)6]2+[\text{Ti(H}_2\text{O)}_6]^{2+}, Titanium is in the +2+2 oxidation state. The electronic configuration of Ti2+\text{Ti}^{2+} is [Ar]3d2[\text{Ar}] 3d^{2}. Since it has partially filled 3d3d orbitals, it can undergo d−dd-d transitions, which are responsible for its color.

The atomic number of Zinc (Zn) is 3030. Its ground state electronic configuration is [Ar]3d104s2[\text{Ar}] 3d^{10} 4s^{2}.

In the complex [Zn(H2O)6]2+[\text{Zn(H}_2\text{O)}_6]^{2+}, Zinc is in the +2+2 oxidation state. The electronic configuration of Zn2+\text{Zn}^{2+} is [Ar]3d10[\text{Ar}] 3d^{10}. Since it has completely filled 3d3d orbitals, d−dd-d transitions are not possible, making the complex colorless.

Thus, Zinc has completely filled 3d3d orbitals and Titanium has partially filled 3d3d orbitals.

Answer: Zinc has completely filled 3d orbitals and Titanium has partially filled 3d orbitals.
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