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MHT CET Medical202625 April 2026Evening ShiftChemistryCoordination CompoundsActual

[ Ti(H ₂ O) ₆]²⁺ is a colored compound where as [ Zn(H ₂ O) ₆]²⁺ is colorless, because

Options

  1. ATitanium has completely filled 3d orbitals and Zinc has partially filled 3d orbitals.
  2. BZinc has completely filled 3d orbitals and Titanium has partially filled 3d orbitals.
  3. CZinc has completely filled 4d orbitals.
  4. DTitanium has completely filled 4d orbitals.

Correct answer

B. Zinc has completely filled 3d orbitals and Titanium has partially filled 3d orbitals.

Step-by-step solution

The atomic number of Titanium (Ti) is 22 . Its ground state electronic configuration is [ Ar ] 3d² 4s² . In the complex [ Ti(H ₂ O) ₆]²⁺ , Titanium is in the +2 oxidation state. The electronic configuration of Ti ²⁺ is [ Ar ] 3d² . Since it has partially filled 3d orbitals, it can undergo d-d transitions, which are responsible for its color. The atomic number of Zinc (Zn) is 30 . Its ground state electronic configuration is [ Ar ] 3d¹⁰ 4s² . In the complex [ Zn(H ₂ O) ₆]²⁺ , Zinc is in the +2 oxidation state. The e

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