MHT CET 202621 AprilMorning Shift
- Exam
- MHT CET
- Year
- 2026
- Date
- 21 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- General Organic Chemistry
MHT CET 2026 · 21 April · Morning Shift · Chemistry · General Organic Chemistry
Compare the relative stability of given carbocations. CH_3- + C...
Compare the relative stability of given carbocations.
(I) (II) (III)
(I) (II) (III)
Options
- AIII > II > I
- BII > I > III
- CI > III > II
- DI > II > III
Correct answer
D. I > II > III
Step-by-step solution
The stability of alkyl carbocations is determined by the +I effect of alkyl groups and hyperconjugation.
Carbocation I is a tertiary (3^{{}^{\circ}}-hydrogens, providing maximum hyperconjugation and +I effect.
Carbocation II is a secondary (2^{{}^{\circ}}-hydrogens.
Carbocation III is a primary (1^{{}^{\circ}}-hydrogens.
More the number of -hydrogens, more is the hyperconjugation and greater is the stability.
Thus, the relative stability order is I > II > III.
Answer: I > II > III
Carbocation I is a tertiary (3^{{}^{\circ}}-hydrogens, providing maximum hyperconjugation and +I effect.
Carbocation II is a secondary (2^{{}^{\circ}}-hydrogens.
Carbocation III is a primary (1^{{}^{\circ}}-hydrogens.
More the number of -hydrogens, more is the hyperconjugation and greater is the stability.
Thus, the relative stability order is I > II > III.
Answer: I > II > III