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MHT CET 202621 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
21 April
Shift
Morning Shift
Subject
Chemistry
Chapter
General Organic Chemistry

MHT CET 2026 · 21 April · Morning Shift · Chemistry · General Organic Chemistry

Compare the relative stability of given carbocations. CH_3- + C...

Compare the relative stability of given carbocations.
CH3-C+-(CH3)2\text{CH}_3\text{-}\overset{+}{\text{C}}\text{-(CH}_3)_2 (I)CH3-C+H-CH3\qquad\text{CH}_3\text{-}\overset{+}{\text{C}}\text{H-CH}_3 (II)CH3-C+H2\qquad\text{CH}_3\text{-}\overset{+}{\text{C}}\text{H}_2 (III)

Options

  1. AIII > II > I
  2. BII > I > III
  3. CI > III > II
  4. DI > II > III

Correct answer

D. I > II > III

Step-by-step solution

The stability of alkyl carbocations is determined by the +I effect of alkyl groups and hyperconjugation.

Carbocation I is a tertiary (3^{{}^{\circ}})carbocationwith9α) carbocation with 9 \alpha-hydrogens, providing maximum hyperconjugation and +I effect.

Carbocation II is a secondary (2^{{}^{\circ}})carbocationwith6α) carbocation with 6 \alpha-hydrogens.

Carbocation III is a primary (1^{{}^{\circ}})carbocationwith3α) carbocation with 3 \alpha-hydrogens.

More the number of α\alpha-hydrogens, more is the hyperconjugation and greater is the stability.

Thus, the relative stability order is I > II > III.

Answer: I > II > III
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