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MHT CET Medical202622 April 2026Evening ShiftChemistryHydrocarbonsActual

Identify the type of reaction when benzene reacts with nitrating mixture.

Options

  1. ASubstitution
  2. BAddition
  3. CElimination
  4. DPolymerization

Correct answer

A. Substitution

Step-by-step solution

Benzene reacts with a nitrating mixture (a mixture of concentrated HNO₃ and concentrated H₂SO₄ ) to form nitrobenzene. In this process, the nitrating mixture generates the nitronium ion ( NO₂^+ ), which acts as an electrophile. The electrophile attacks the electron-rich benzene ring, replacing one of its hydrogen atoms with a nitro group ( -NO₂ ). Since a hydrogen atom is replaced by another group, this is an electrophilic aromatic substitution reaction. Answer: Substitution

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