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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Hydrocarbons

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Hydrocarbons

Which one of the following alkenes forms the same product with HBr...

Which one of the following alkenes forms the same product with HBr in the absence as well as in the presence of peroxide?

Options

  1. A2-butene
  2. B1-butene
  3. Cpropene
  4. D2-methyl propene

Correct answer

A. 2-butene

Step-by-step solution

Symmetrical alkenes yield the same product with HBr in the presence and absence of peroxide because both carbons of the double bond are equivalent.

2-butene (CH_3-CH=CH-CH_3)isasymmetricalalkene.<br><br>AdditionofHBrto2−buteneintheabsenceofperoxide(electrophilicaddition)yields2−bromobutane.<br><br>AdditionofHBrto2−buteneinthepresenceofperoxide(freeradicaladdition)alsoyields2−bromobutane.<br><br>1−butene,propene,and2−methylpropeneareunsymmetricalalkenesandwillyielddifferentproducts(Markovnikovandanti−Markovnikovproducts)underthesetwoconditions.<br><br>Answer:2−butene) is a symmetrical alkene.<br><br>Addition of HBr to 2-butene in the absence of peroxide (electrophilic addition) yields 2-bromobutane.<br><br>Addition of HBr to 2-butene in the presence of peroxide (free radical addition) also yields 2-bromobutane.<br><br>1-butene, propene, and 2-methylpropene are unsymmetrical alkenes and will yield different products (Markovnikov and anti-Markovnikov products) under these two conditions.<br><br>Answer: 2-butene
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