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MHT CET Medical202625 April 2026Evening ShiftChemistryHydrocarbonsActual

Which one of the following alkenes forms the same product with HBr in the absence as well as in the presence of peroxide?

Options

  1. A2-butene
  2. B1-butene
  3. Cpropene
  4. D2-methyl propene

Correct answer

A. 2-butene

Step-by-step solution

Symmetrical alkenes yield the same product with HBr in the presence and absence of peroxide because both carbons of the double bond are equivalent. 2-butene ( CH₃-CH=CH-CH₃ ) is a symmetrical alkene. Addition of HBr to 2-butene in the absence of peroxide (electrophilic addition) yields 2-bromobutane. Addition of HBr to 2-butene in the presence of peroxide (free radical addition) also yields 2-bromobutane. 1-butene, propene, and 2-methylpropene are unsymmetrical alkenes and will yield different products (Markovnikov

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