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MHT CET 202622 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
22 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

MHT CET 2026 · 22 April · Evening Shift · Chemistry · Solutions

Which of the following statements is NOT true about the ideal...

Which of the following statements is NOT true about the ideal solution?

Options

  1. AIt obeys Raoult's law over the entire range of concentration.
  2. BThere is no heat evolved or absorbed when two components forming an ideal solution are mixed.
  3. CThere is no volume change when two components forming an ideal solution are mixed.
  4. DThe vapor pressure of the ideal solution can be higher or lower than those of pure components

Correct answer

D. The vapor pressure of the ideal solution can be higher or lower than those of pure components

Step-by-step solution

For an ideal solution, the following conditions hold true:

1. It obeys Raoult's law over the entire range of concentration.

2. The enthalpy of mixing is zero, i.e., ΔHmix=0\Delta H_{mix} = 0. No heat is evolved or absorbed.

3. The volume of mixing is zero, i.e., ΔVmix=0\Delta V_{mix} = 0.

4. The total vapor pressure of the solution is given by Ptotal=PA0xA+PB0xBP_{total} = P_A^{0} x_{A} + P_B^{0} x_{B}. Since xA+xB=1x_{A} + x_{B} = 1, the total vapor pressure is a weighted average of the vapor pressures of the pure components. Therefore, the vapor pressure of an ideal solution always lies between the vapor pressures of the pure components. It cannot be higher or lower than both.

Thus, the statement that the vapor pressure of the ideal solution can be higher or lower than those of pure components is incorrect.

Answer: The vapor pressure of the ideal solution can be higher or lower than those of pure components
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