AIIMS 2017
- Exam
- AIIMS
- Year
- 2017
- Subject
- Chemistry
- Chapter
- p Block Elements (Group 15, 16, 17 & 18)
AIIMS 2017 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)
Assertion : Hydrides of group-16 elements show volatility in the...
Assertion : Hydrides of group-16 elements show volatility in the order:
Reason : Electronegativity of group-16 elements increases down the group from oxygen to tellurium.
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- CIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Correct answer
D. If both assertion and reason are false.
Step-by-step solution
Hydrides of group-16 elements show volatility in the order :
Oxygen is most electronegative than other elements of group-16, it undergoes hydrogen bonding. Due to strong intermolecular hydrogen bonding in , it shows lowest volatility.
As the size of the atom increases regularly from sulphur to tellurium, van der Waals' forces of attraction increase and hence volatility decreases from to .