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NEET 2024
Exam
NEET
Year
2024
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

NEET 2024 · Chemistry · Chemical Bonding and Molecular Structure

Identify the incorrect statement about PCl_5 .

Identify the incorrect statement about PCl5\mathrm{PCl}_5.Identify the incorrect statement about PCl_5 .

Options

  1. APCl5\mathrm{PCl}_5 possesses two different Cl−P−Cl\mathrm{Cl}-\mathrm{P}-\mathrm{Cl} bond angles
  2. BAll five P−Cl\mathrm{P}-\mathrm{Cl} bonds are identical in length
  3. CPCl5\mathrm{PCl}_5 exhibits sp3ds p^3 d hybridisation
  4. DPCl5\mathrm{PCl}_5 consists of five P−Cl\mathrm{P}-\mathrm{Cl} (sigma) bonds

Correct answer

B. All five P−Cl\mathrm{P}-\mathrm{Cl} bonds are identical in length

Step-by-step solution

Identify the incorrect statement about PCl_5 .
It is sp3ds p^3 d hybridised with axial to equatorial angle of 90∘90^{\circ} and equatorial bond angles of 120∘120^{\circ}. It has five P−Cl\mathrm{P}-\mathrm{Cl} sigma bonds. Axial bonds are longer than equatorial bonds.
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