NEET2023ChemistryChemical Bonding and Molecular StructureActual
The correct order of energies of molecular orbitals of N 2 molecule, is:
Options
- A( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < ( π
- B( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < ( π
- C( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < σ 2
- D( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < σ 2
Correct answer
B. ( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < ( π
Step-by-step solution
The molecular orbitals filled with electrons according Afbaue, Pauli's exclusion and Hund's rules. ( σ 1 s ) < ( σ * 1 s ) <   ( σ 2 s ) <   ( σ 2 s * ) < ( π 2 p x ) = ( π 2 p y ) < σ 2 p z < ( π * 2 p x ) = ( π * 2 p y ) < ( σ * 2 p z ) The important characteristic feature of this order is that the energy of σ 2 pz molecular orbital is higher than that of π 2 px   and   π 2 py molecular orbital