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NEET 2022
Exam
NEET
Year
2022
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

NEET 2022 · Chemistry · Chemical Bonding and Molecular Structure

The decreasing order of boiling points of the following alkanes is:...

The decreasing order of boiling points of the following alkanes is: (a) Heptane (b) butane (c) 2-methylbutane (d) 2-methylpropane (e) hexane Choose the correct answer from the options given below:

Options

  1. A(a) >> (c) >> (e) >> (d) >> (b)
  2. B(c) >> (d) >> (a) >> (e) >> (b)
  3. C(a) >> (e) >> (b) >> (c) >> (d)
  4. D(a) >> (e) >> (c) >> (b) >> (d)

Correct answer

D. (a) >> (e) >> (c) >> (b) >> (d)

Step-by-step solution

With increase in molecular mass, van Der Waal force increases and hence boiling point also increases. ∴\therefore BP : Heptane >> Hexane >> 2- Methyl Butane >> Butane >> 2- methly propane with the increase in branching, surface area decreases of molecules of same molecular mass which results in decrease in boiling point.
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