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NEET2011ChemistryChemical Bonding and Molecular StructureActual

Which of the two ions from the list given below, have the geometry that is explained by the same hybridisation of orbitals, NO ₂⁻, NO ₃⁻, NH ₂⁻, NH ₄⁺, SCN ⁻ ?

Options

  1. ANH ₄⁺ and NO ₃⁻
  2. BSCN ⁻ and NH ₂⁻
  3. CNO ₂⁻ and NH ₂⁻
  4. DNO ₂⁻ and NO ₃⁻

Correct answer

D. NO ₂⁻ and NO ₃⁻

Step-by-step solution

array ll NO ₂⁻ & s p^2 NO ₃⁻ & s p^2 NH ₂⁺ & s p^3 array array ll NH ₄⁻ & s p^3 SCN ⁻ & s p array NO ₂⁻ and NO ₃⁻ both have the same hybridisation. [ Co ( H ₂ O )₆ ]²⁺ has minimum number of unpaired electrons and thus, minimum paramagnetic behaviour.

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