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NEET2010ChemistryChemical Bonding and Molecular StructureActual

Some of the properties of the two species, NO ₃⁻ and H ₃ O ⁺ are described below. Which one of them is correct?

Options

  1. ADissimilar in hybridisation for the central atom with different structures
  2. BIsostructural with same hybridisation for the central atom
  3. CIsostructural with different hybridisation for the central atom
  4. DSimilar in hybridisation for the central atom with different structures

Correct answer

A. Dissimilar in hybridisation for the central atom with different structures

Step-by-step solution

aligned & In NO ₃⁻, & H = 1 2 [5+0-0+1]=3 aligned Thus, in NO ₃⁻ , the central atom is sp ^2 hybridised and it has trigonal planar geometry. In H ₃ O ⁺ , H = 1 2 [6+3-1+0]=4 Thus, O is sp ^3 hybridised in H ₃ O ⁺ and H ₃ O ⁺ has pyramidal geometry due to the presence of one lone pair of electrons.

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