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NEET 2002
Exam
NEET
Year
2002
Subject
Chemistry
Chapter
Chemical Equilibrium

NEET 2002 · Chemistry · Chemical Equilibrium

For the reaction BaO_2(s) leftharpoons BaO(s)+O_2(g) ; Δ H=+ve . In...

For the reaction BaO2(s)⇌BaO(s)+O2(g);ΔH=+ve. Inanequilibriumcondition,pressureof\mathrm{BaO}_2(s) \rightleftharpoons \mathrm{BaO}(s)+\mathrm{O}_2(g) ; \Delta \mathrm{H}=+\mathrm{ve} \text{. } In an equilibrium condition, pressure ofO2\mathrm{O}_2dependson:depends on:

Options

  1. Aincreased mass of BaO2\mathrm{BaO}_2
  2. Bincreased mass of BaO\mathrm{BaO}
  3. Cincreased temperature at equilibrium
  4. Dincreased mass of both BaO2\mathrm{BaO}_2 and BaO\mathrm{BaO}

Correct answer

C. increased temperature at equilibrium

Step-by-step solution

For the reaction 2BaO2( s)⇌BaO(s)+O2( g);ΔH=+ve2 \mathrm{BaO}_2(\mathrm{~s}) \rightleftharpoons \mathrm{BaO}(\mathrm{s})+\mathrm{O}_2(\mathrm{~g}) ; \Delta \mathrm{H}= +\mathrm{ve} In equillibrium KP=PO2\mathrm{K}_P=\mathrm{PO}_2 Hence, the value of equilibrium constant depends only upon partial pressure of O2\mathrm{O}_2. Further on increasing temperature formation of O2\mathrm{O}_2 increases as this is an endothermic reaction. Hence, pressure of O2\mathrm{O}_2 is dependent on temperature.
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