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NEET 2023
Exam
NEET
Year
2023
Subject
Chemistry
Chapter
Electrochemistry

NEET 2023 · Chemistry · Electrochemistry

Molar conductance of an electrolyte increases with dilution...

Molar conductance of an electrolyte increases with dilution according to the equation: Λm=Λm∘−Ac\Lambda_{\mathrm{m}}=\Lambda_{\mathrm{m}}^{\circ}-\mathrm{A} \sqrt{\mathrm{c}} Which of the following statements are true? (A) This equation applies to both strong and weak electrolytes. (B) Value of the constant A depends upon the nature of the solvent. (C) Value of constant A\mathrm{A} is same for both BaCl2\mathrm{BaCl}_2 and MgSO4\mathrm{MgSO}_4. (D) Value of constant AA is same for both BaCl2\mathrm{BaCl}_2 and Mg(OH)2\mathrm{Mg}(\mathrm{OH})_2. Choose the most appropriate answer from the options given below.

Options

  1. A(B) and (C) only
  2. B(B) and (D) only
  3. C(A) and (B) only
  4. D(A),(B)(A),(B) and (C)(C) only

Correct answer

B. (B) and (D) only

Step-by-step solution

Λm=Λm∘−Ac\Lambda_m=\Lambda_m^{\circ}-A \sqrt{c} - For strong electrolytes, Λm\Lambda_{\mathrm{m}} increases slowly with dilution. - The value of ' AA ' depends on the type of electrolyte. - All electrolytes of particular type have the same value for 'A' e.g. BaCl2\mathrm{BaCl}_2 and Mg(OH)2→2−1\mathrm{Mg}(\mathrm{OH})_2 \rightarrow 2-1 electrolytes
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