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NEET 2024
Exam
NEET
Year
2024
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2024 · Chemistry · General Organic Chemistry

Given below are two statements: Statement I : The boiling point of...

Given below are two statements: Statement I : The boiling point of three isomeric pentanes follows the order n-pentane >\gt isopentane >\gt neopentane Statement II : When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. ABoth Statement I and Statement II are incorrect
  2. BStatement I is correct but Statement II is incorrect
  3. CStatement I is incorrect but Statement II is correct
  4. DBoth Statement I and Statement II are correct

Correct answer

D. Both Statement I and Statement II are correct

Step-by-step solution

Both statement I and statement II are correct.  Boiling point of n-pentane =309K isopentane =301K neopentane =282.5\begin{array}{r} \text{ Boiling point of } n \text{-pentane }=309 \mathrm{ K} \\ \text{ isopentane }=301 \mathrm{ K} \\ \text{ neopentane }=282.5 \end{array}As branching increases molecules attain the shape of a sphere results in smaller area of contact thus weak intermolecular forces between spherical molecules, which are overcome at relatively lower temperature. Leading to decrease in boiling point.$
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