NEET2024ChemistryGeneral Organic ChemistryActual
Given below are two statements: Statement I : The boiling point of three isomeric pentanes follows the order n-pentane isopentane neopentane Statement II : When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. In the light of the above state
Options
- ABoth Statement I and Statement II are incorrect
- BStatement I is correct but Statement II is incorrect
- CStatement I is incorrect but Statement II is correct
- DBoth Statement I and Statement II are correct
Correct answer
D. Both Statement I and Statement II are correct
Step-by-step solution
Both statement I and statement II are correct. array r Boiling point of n -pentane =309 ~K isopentane =301 ~K neopentane =282.5 array As branching increases molecules attain the shape of a sphere results in smaller area of contact thus weak intermolecular forces between spherical molecules, which are overcome at relatively lower temperature. Leading to decrease in boiling point.