Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
NEET 2019
Exam
NEET
Year
2019
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2019 · Chemistry · General Organic Chemistry

The correct order of the basis strength of methyl substituted...

The correct order of the basis strength of methyl substituted amines in aqueous solution is:

Options

  1. A(CH3)2NH>CH3NH2>(CH3)3N{\left(C{H}_{3}\right)}_{2}NH > C{H}_{3}N{H}_{2} > {\left(C{H}_{3}\right)}_{3}N
  2. B(CH3)3N>CH3NH2>(CH3)2NH{\left(C{H}_{3}\right)}_{3}N > C{H}_{3}N{H}_{2} > {\left(C{H}_{3}\right)}_{2}NH
  3. C(CH3)3N>(CH3)2NH>CH3NH2{\left(C{H}_{3}\right)}_{3}N > {\left(C{H}_{3}\right)}_{2}N{H}_{} > {CH}_{3}N{H}_{2}
  4. DCH3NH2>(CH3)2NH>(CH3)3NC{H}_{3}N{H}_{2} > {\left(C{H}_{3}\right)}_{2}NH > {\left(C{H}_{3}\right)}_{3}N

Correct answer

A. (CH3)2NH>CH3NH2>(CH3)3N{\left(C{H}_{3}\right)}_{2}NH > C{H}_{3}N{H}_{2} > {\left(C{H}_{3}\right)}_{3}N

Step-by-step solution

Combined effect of the inductive effect of Alkyl group (+I),\left(+ I\right), steric hindrance and the salvation of Amines causes the basicity order to be Secondary Amine > Primary Amine > Tertiary Amine

(CH3)2NH>CH3NH2>(CH3)3N{\left(C{H}_{3}\right)}_{2}NH > C{H}_{3}N{H}_{2} > {\left(C{H}_{3}\right)}_{3}N

Practice General Organic Chemistry on Quantrex Academy →

More from General Organic Chemistry

Identify the overlapping orbitals involved in hyperconjugation from following. MHT CET Medical 2026What is the IUPAC name of (CH_3)_2CH-COOH ? MHT CET Medical 2026What is the IUPAC name of the following compound? MHT CET Medical 2026CH_3-CH=CH-CH_2-COOH What is the IUPAC name of the above compound ? MHT CET Medical 2026What is IUPAC name of the following organic compound? MHT CET Medical 2026Which of the following exhibits - I effect? MHT CET Medical 2026Which of the following statement is NOT correct about a racemic mixture? MHT CET Medical 2026What type of isomerism is found in but-2-ene? MHT CET Medical 2026 Full General Organic Chemistry list All NEET PYQs