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NEET 2018
Exam
NEET
Year
2018
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2018 · Chemistry · General Organic Chemistry

Which of the following carbocations is expected to be the most...

Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?Which of the following carbocations is expected to be the most stable?

Options

  1. AThe difference in lengths of a mean solar day and a sidereal day is about
  2. BThe difference in lengths of a mean solar day and a sidereal day is about
  3. CThe difference in lengths of a mean solar day and a sidereal day is about
  4. DThe difference in lengths of a mean solar day and a sidereal day is about

Correct answer

A. The difference in lengths of a mean solar day and a sidereal day is about

Step-by-step solution

NO2{NO}_{2} is present at the ortho- and the para- position of a positive charge.

NO2{NO}_{2} present at the meta-position of a positive charge is less stable due to the e−{e}^{-} withdrawing effect of −NO2- {NO}_{2} (−I- I effect of NO2{NO}_{2})

Which of the following carbocations is expected to be the most stable?

NO2{NO}_{2} present at the ortho- and para- of positive charge (Less stable due to the e−{e}^{-} withdrawing effect of −NO2- {NO}_{2} (−M- M effect.)

Which of the following carbocations is expected to be the most stable?

The positive charge is destabilized by the electron-withdrawing groups.
−M- M dominates −I- I effect. So, the carbocation which has −I- I group is more stable.

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