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NEET2016ChemistryGeneral Organic ChemistryActual

The correct statement regarding the basicity of aryl amines is:

Options

  1. AAryl amines are generally less basic than alkyl amines because the nitrogen lone-pair electrons are delocalize
  2. BAryl amines are generally more basic than alkyl amines because the nitrogen lone-pair electrons are not deloca
  3. CAryl amines are generally more basic than alkyl amines because of aryl group.
  4. DAryl amines are generally more basic than alkyl amines, because the nitrogen atom in aryl amines is sp-hybridi

Correct answer

A. Aryl amines are generally less basic than alkyl amines because the nitrogen lone-pair electrons are delocalize

Step-by-step solution

In Aryl amines lone pair is in conjugation with double bond so basic strength decreased While in aliphatic amine ( R − N H 2 ) no delocalisation of lone pair and +I effect of − CH 3 group so they have more basic strength.

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