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NEET 2016
Exam
NEET
Year
2016
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2016 · Chemistry · General Organic Chemistry

The correct statement regarding the basicity of aryl amines is:

The correct statement regarding the basicity of aryl amines is:The correct statement regarding the basicity of aryl amines is:

Options

  1. AAryl amines are generally less basic than alkyl amines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π\pi electron system.
  2. BAryl amines are generally more basic than alkyl amines because the nitrogen lone-pair electrons are not delocalized by interaction with the aromatic ring π\pi electron system.
  3. CAryl amines are generally more basic than alkyl amines because of aryl group.
  4. DAryl amines are generally more basic than alkyl amines, because the nitrogen atom in aryl amines is sp-hybridized.

Correct answer

A. Aryl amines are generally less basic than alkyl amines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π\pi electron system.

Step-by-step solution

The correct statement regarding the basicity of aryl amines is:

In Aryl amines lone pair is in conjugation with double bond so basic strength decreased

While in aliphatic amine (R−NH2)( \text{R} - \text{N}{\text{H}}_{2} ) no delocalisation of lone pair and +I effect of −CH3- {\text{CH}}_{\text{3}} group so they have more basic strength.

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