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NEET2012ChemistryGeneral Organic ChemistryActual

Among the following compounds the one that is most reactive towards electrophilic nitration is

Options

  1. Abenzoic acid
  2. Bnitrobenzene
  3. Ctoluene
  4. Dbenzene

Correct answer

C. toluene

Step-by-step solution

Presence of electron releasing group like -R,- OH etc., increases the electron density at o / p position and thus, makes the benzene ring more reactive (at o / p positions) towards electrophile. On the other hand, electron withdrawing group like - COOH ,- NO ₂ etc., if present, reduces electron density and thus, reduces the activity of benzene nucleus towards electrophile. Thus, the order of the given compounds towards electrophilic nitration is Thus, toluene is most reactive towards electrophilic nitration.

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