NEET2010ChemistryGeneral Organic ChemistryActual
Given are cyclohexanol (I), acetic acid (II), 2, 4, 6-trinitrophenol (III) and phenol (IV). In these, the order of decreasing acidic character will be
Options
- AIII > II > IV > I
- BII > III > I > IV
- CII > III > IV > I
- DIII > IV > II > I
Correct answer
A. III > II > IV > I
Step-by-step solution
Key Idea:- Higher the tendency to give a proton, higher is the acidic character, and tendency to lose a proton depends upon the stability of intermediate, ie, carbanion formed. 2, 4, 6-trinitrophenol after the loss of a proton gives 2,4,6-trinitrophenoxide ion which is stabilised by resonance, -I effect and -M effect, thus is most acidic among the given compounds. Phenol after losing a proton form phenoxide ion which is also stabilised by resonance, -M and -I effects but is less stabilised as compared to 2, 4, 6-tr