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NEET 2008
Exam
NEET
Year
2008
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2008 · Chemistry · General Organic Chemistry

The stability of carbanions in the following (1) RC C (2) (3)(R_2...

The stability of carbanions in the following (1) RC≡C⊖\mathrm{RC} \equiv \stackrel{\ominus}{\mathrm{C}}
(2)The stability of carbanions in the following (1) RC C (2) (3)(R_2 C= C H) (4) R_3 C- C H_2 is in the order of
(3)(\mathrm{R}_2 \mathrm{C}=\stackrel{\ominus}{\mathrm{C}}\mathrm{H})
(4) R3C−C⊖H2\mathrm{R}_3 \mathrm{C}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_2 is in the order of

Options

  1. A(1) >> (2) >> (3) >> (4)
  2. B(2)>(3)>(4)>(1)(2)>(3)>(4)>(1)
  3. C(4) >> (2) >> (3) >> (1)
  4. D(1) >> (3) >> (2) >> (4)

Correct answer

A. (1) >> (2) >> (3) >> (4)

Step-by-step solution

Key Idea : When scharacter increases, then electrons becomes more closer to the nucleus and structure is of lower energy and is more stable. The stability order of carbanions is as : RC≡C⊖\mathrm{RC} \equiv \mathrm{C}^{\ominus}>C6H\mathrm{C}_{6} \mathrm{H}}_{5}^{\ominus}>R2C=C⊖H>R\mathrm{R}_{2} \mathrm{C}=\stackrel{\ominus}{\mathrm{C}} \mathrm{H}> \mathrm{R}}_{3} C−C⊖H2\mathrm{C}-\stackrel{\ominus}{\mathrm{C}} \mathrm{H}_{2}
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