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NEET2003ChemistryGeneral Organic ChemistryActual

Which one of the following orders of acid strength is correct?

Options

  1. ARCOOH > ROH > HOH > HC HC
  2. BRCOOH > HOH > ROH > HC CH
  3. CRCOOH > HOH > HC CH > ROH
  4. DRCOOH > HC CH > HOH > ROH

Correct answer

B. RCOOH > HOH > ROH > HC CH

Step-by-step solution

Carboxylic acids are most acidic and alcohols are least acidic. Phenols are more acidic than alcohols but less acidic than carboxylic acids or carbonic acid. Thus, acidic strength order is ( R - || O C - OH > H - O - H > R - O - H > H - C C - H ) Related Theory Acid strength increases with : 1. increasing electronegativity of the central atom: The more electronegative the central atom, the more electron drift occurs, polarizing the O - H bond which makes it easier for the molecule to dissociate. 2. increasing oxida

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