NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Hydrocarbons
NEET 2026 · Chemistry · Hydrocarbons
Consider the following reaction, and choose the correct option.
Consider the following reaction, and choose the correct option.

Options
- ACompound is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO.
- BOn treating compound with saturated NaHCO solution, brisk effervescence is observed.
- CCompound can be prepared by treating benzene with anhydrous AlCl and CHCOCl.
- DOn treatment with bromine water, compound gives a white precipitate.
Correct answer
A. Compound is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO.
Step-by-step solution
The given reaction is the Etard reaction. Toluene reacts with chromyl chloride () in a non-polar solvent like to form a chromium complex, which upon acid hydrolysis () yields benzaldehyde.
Therefore, compound is benzaldehyde ().
Let us evaluate the given options:
Option (1): The hydrogenation of benzoyl chloride () with in the presence of Pd supported on is known as the Rosenmund reduction. This reaction yields benzaldehyde. Thus, this statement is correct.
Option (2): Benzaldehyde does not react with saturated solution to give brisk effervescence. This test is characteristic of carboxylic acids.
Option (3): Treating benzene with anhydrous and acetyl chloride () is a Friedel-Crafts acylation reaction, which produces acetophenone (), not benzaldehyde.
Option (4): Benzaldehyde does not give a white precipitate with bromine water. The bromine water test giving a white precipitate is characteristic of phenol and aniline.
Answer: Compound is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO.
Therefore, compound is benzaldehyde ().
Let us evaluate the given options:
Option (1): The hydrogenation of benzoyl chloride () with in the presence of Pd supported on is known as the Rosenmund reduction. This reaction yields benzaldehyde. Thus, this statement is correct.
Option (2): Benzaldehyde does not react with saturated solution to give brisk effervescence. This test is characteristic of carboxylic acids.
Option (3): Treating benzene with anhydrous and acetyl chloride () is a Friedel-Crafts acylation reaction, which produces acetophenone (), not benzaldehyde.
Option (4): Benzaldehyde does not give a white precipitate with bromine water. The bromine water test giving a white precipitate is characteristic of phenol and aniline.
Answer: Compound is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO.