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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Hydrocarbons

NEET 2026 · Chemistry · Hydrocarbons

Consider the following reaction, and choose the correct option.

Consider the following reaction, and choose the correct option.
Consider the following reaction, and choose the correct option.

Options

  1. ACompound P\text{P} is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO4_4.
  2. BOn treating compound P\text{P} with saturated NaHCO3_3 solution, brisk effervescence is observed.
  3. CCompound P\text{P} can be prepared by treating benzene with anhydrous AlCl3_3 and CH3_3COCl.
  4. DOn treatment with bromine water, compound P\text{P} gives a white precipitate.

Correct answer

A. Compound P\text{P} is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO4_4.

Step-by-step solution

The given reaction is the Etard reaction. Toluene reacts with chromyl chloride (CrO2Cl2\text{CrO}_2\text{Cl}_2) in a non-polar solvent like CS2\text{CS}_2 to form a chromium complex, which upon acid hydrolysis (H3O+\text{H}_3\text{O}^+) yields benzaldehyde.

Therefore, compound P\text{P} is benzaldehyde (C6H5CHO\text{C}_6\text{H}_5\text{CHO}).

Let us evaluate the given options:

Option (1): The hydrogenation of benzoyl chloride (C6H5COCl\text{C}_6\text{H}_5\text{COCl}) with H2\text{H}_2 in the presence of Pd supported on BaSO4\text{BaSO}_4 is known as the Rosenmund reduction. This reaction yields benzaldehyde. Thus, this statement is correct.

Option (2): Benzaldehyde does not react with saturated NaHCO3\text{NaHCO}_3 solution to give brisk effervescence. This test is characteristic of carboxylic acids.

Option (3): Treating benzene with anhydrous AlCl3\text{AlCl}_3 and acetyl chloride (CH3COCl\text{CH}_3\text{COCl}) is a Friedel-Crafts acylation reaction, which produces acetophenone (C6H5COCH3\text{C}_6\text{H}_5\text{COCH}_3), not benzaldehyde.

Option (4): Benzaldehyde does not give a white precipitate with bromine water. The bromine water test giving a white precipitate is characteristic of phenol and aniline.

Answer: Compound P\text{P} is obtained by the hydrogenation of benzoyl chloride with Pd on BaSO4_4.
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