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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Hydrocarbons

NEET 2026 · Chemistry · Hydrocarbons

Given below are two statements: Statement I: trans -But-2-ene upon...

Given below are two statements:
Statement I:
trans-But-2-ene upon treatment with Br2_2 in CCl4_4 gives the following product
Given below are two statements: Statement I: trans -But-2-ene upon treatment with Br _2 in CCl _4 gives the following
Statement II:
cis-But-2-ene upon treatment with alkaline KMnO4_4 gives the following product
Given below are two statements: Statement I: trans -But-2-ene upon treatment with Br _2 in CCl _4 gives the following
In the light of the above statements, choose the most appropriate answer from the options given below.

Options

  1. AStatement I is incorrect but Statement II is correct
  2. BBoth Statement I and Statement II are correct
  3. CBoth Statement I and Statement II are incorrect
  4. DStatement I is correct but Statement II is incorrect

Correct answer

A. Statement I is incorrect but Statement II is correct

Step-by-step solution

Reaction of trans-but-2-ene with Br2_2 in CCl4_4 proceeds via anti-addition to give meso-2,3-dibromobutane.

In the Newman projection given in Statement I, the front carbon has Br at 0∘0^{\circ}, Me at 120∘120^{\circ}, and H at 240∘240^{\circ}. The back carbon has Br at 180∘180^{\circ}, Me at 60∘60^{\circ}, and H at 300∘300^{\circ}. For this staggered conformation to be meso, it must have a center of inversion, meaning a group at angle θ\theta on the front carbon must have an identical group at θ+180∘\theta + 180^{\circ} on the back carbon. While the Br atoms are opposite (0∘0^{\circ} and 180∘180^{\circ}), the front Me at 120∘120^{\circ} is not opposite to the back Me at 60∘60^{\circ}. Thus, it lacks a center of inversion and represents a chiral enantiomer. Hence, Statement I is incorrect.

Reaction of cis-but-2-ene with alkaline KMnO4_4 proceeds via syn-addition to give meso-butane-2,3-diol.

In the Newman projection given in Statement II, the front carbon has OH at 0∘0^{\circ}, Me at 120∘120^{\circ}, and H at 240∘240^{\circ}. The back carbon has OH at 60∘60^{\circ}, Me at 180∘180^{\circ}, and H at 300∘300^{\circ}. Rotating the back carbon by 60∘60^{\circ} counter-clockwise perfectly eclipses all identical groups (OH with OH at 0∘0^{\circ}, Me with Me at 120∘120^{\circ}, H with H at 240∘240^{\circ}). This indicates the presence of a plane of symmetry, confirming it is the meso isomer. Hence, Statement II is correct.

Therefore, Statement I is incorrect but Statement II is correct.

Answer: Statement I is incorrect but Statement II is correct
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