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NEET2008Chemistryp Block Elements (Group 15, 16, 17 & 18)Actual

The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The thermal stability of these hydrides decreases in which of the following orders?

Options

  1. ACsH > RbH > KH > NaH > LiH
  2. BKH > NaH > LiH > CsH > RbH
  3. CNaH > LiH > KH > RbH > CsH
  4. DLiH > NaH > KH > RbH > CsH

Correct answer

D. LiH > NaH > KH > RbH > CsH

Step-by-step solution

Key Idea : Small anion forms stable compounds with small cation. The thermal stability of alkali metal hydrides decreases as : LiH > NaH > KH > RbH > CsH because the size of cation increases as : Li ⁺ < Na ⁺ < K ⁺ < Rb ⁺ < Cs ⁺

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