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NEET2007Chemistryp Block Elements (Group 15, 16, 17 & 18)Actual

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

Options

  1. AHOClO < HOCl < HOClO ₃ < HOClO ₂
  2. BHOClO ₂ < HOClO ₃ < HOClO < HOCl
  3. CHOClO ₃ < HOClO ₂ < HOClO < HOCl
  4. DHOCl < HOClO < HOClO ₂ < HOClO ₃

Correct answer

D. HOCl < HOClO < HOClO ₂ < HOClO ₃

Step-by-step solution

As the oxidation number of the central atom increases, strength of acid also increases. HOCl < HOClO < HOClO ₂ < HOClO ₃ Related Theory The chlorine is more electronegative than bromine. As a result, it will attract electrons more towards itself than bromine. This will result in a donation of H + more easily in HOCl than in HOBr. So, the HOCl will be stronger acid than HOBr .

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