NEET2019ChemistryThermodynamics (C)Actual
Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure. A B Isothermal expansion A C Adiabatic expansion Which of the following option is not correct?
Options
- AS_ isothermal > S_ adiabatic
- BT_A=T_B
- CW_ isothermal >W_ adiabatic
- DT_c>T_A
Correct answer
D. T_c>T_A
Step-by-step solution
From first law of thermodynamics, U = q + W In adiabatic expansion, q=0 U = W During expansion of a gas w is negative i.e w < 0 or U < 0 . We know that, U = nC _ V T array lclc & nC _ V T < 0 & or & T < 0 & T _ C - T _ A < 0 & or & T _ C < T _ A array Thus, option (4) is incorrect while the remaining options are correct.