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NEET2019ChemistryThermodynamics (C)Actual

Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure. A B Isothermal expansion A C Adiabatic expansion Which of the following option is not correct?

Options

  1. AS_ isothermal > S_ adiabatic
  2. BT_A=T_B
  3. CW_ isothermal >W_ adiabatic
  4. DT_c>T_A

Correct answer

D. T_c>T_A

Step-by-step solution

From first law of thermodynamics, U = q + W In adiabatic expansion, q=0 U = W During expansion of a gas w is negative i.e w < 0 or U < 0 . We know that, U = nC _ V T array lclc & nC _ V T < 0 & or & T < 0 & T _ C - T _ A < 0 & or & T _ C < T _ A array Thus, option (4) is incorrect while the remaining options are correct.

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