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AIIMS 2012
Exam
AIIMS
Year
2012
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

AIIMS 2012 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following is the correct statement for PH_3 ?

Which of the following is the correct statement for PH3\mathrm{PH}_3 ?

Options

  1. AIt is less poisonous than NH3\mathrm{NH}_3.
  2. BIt is less basic than NH3\mathrm{NH}_3.
  3. CElectronegativity of PH3>NH3\mathrm{PH}_3>\mathrm{NH}_3.
  4. DIt does not show reducing properties.

Correct answer

B. It is less basic than NH3\mathrm{NH}_3.

Step-by-step solution

Nitrogen is more electronegative and smaller in size than phosphorus. Therefore, the lone pair is concentrated on a small region and has maximum electron density. So, NH3\mathrm{NH}_3 is more basic than PH3\mathrm{PH}_3.
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