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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

NTA Abhyas 2020 · Chemistry · Carboxylic Acid Derivatives

The correct order of acidic strength of the following is (I) Oxalic...

The correct order of acidic strength of the following is
(I) Oxalic acid HOOC−COOHHOOC - COOH
(II) Malonic acid HOOC−CH2−COOHHOOC - C{H}_{2} - COOH
(III) Succinic acid HOOC−(CH2)2−COOHHOOC - {\left(C{H}_{2}\right)}_{2} - COOH
(IV) Glutaric acid HOOC−(CH2)3−COOHHOOC - {\left(C{H}_{2}\right)}_{3} - COOH

Options

  1. AI > II > III > IV
  2. BI > III> II > IV
  3. CIV> III > II > I
  4. DIV> II > III > I

Correct answer

A. I > II > III > IV

Step-by-step solution

Acidic strength of dicarboxylic acid is based on the +I effect of alkyl group. As +I increases acidic nature decreases.
Compounds with formula HOOC−(CH2)n−COOHHOOC - {\left(C{H}_{2}\right)}_{n} - COOH are called dicarboxylic acid.
Acidic strength order is:
Oxalic acid > Malonic acid > Succinic acid > Glutaric acid
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