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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

NTA Abhyas 2020 · Chemistry · Carboxylic Acid Derivatives

A compound with molecular formula C _ 4 H _ 10 O _ 3 in converted...

A compound with molecular formula C4H10O3{C}_{4}{H}_{10}{O}_{3} in converted by the action of acetyl chloride to a compound of molecular mass 190. The original compound (C4H10O3)\left({C}_{4}{H}_{10}{O}_{3}\right) has how many −OH- \text{OH} groups?

Correct answer

2

Step-by-step solution

In acetylation, replacement of H of O−HO - H occurs by CH3CO−C{H}_{3}CO - group. −O−H+ClC∣∣O−CH3→−OCOCH3+HCl- O - H + Cl \overset{O}{\overset{| |}{C}} - C{H}_{3} \to - OCOC{H}_{3} + HCl

i.e., H atom of mass 1 amu is lost and an acetyl group of mass 43 amu is added. Thus, there is a net gain of 43 - 1 = 42 amu for every acetyl group introduced. Mass of difference of final product and original compound is 190 - 106 = 84.

Hence, number of −OH- OH groups =8442=2= \dfrac{84}{42} = 2 .
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