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NTA Abhyas JEE Main2020ChemistryChemical Bonding and Molecular StructurePractice

The Lewis structure of allene is Which of the following statements correctly gives answers for all 3 parts: (a) Is the molecule planar? (b) Does 1, 3 - dichloro propadiene show geometrical isomerism? (c) Is the molecule 1, 3 - dichloro propadiene polar?

Options

  1. A(i) Non-planar (ii) No geometrical isomerism (iii) Polar
  2. B(i) Planar (ii) No geometrical isomerism (iii) Polar
  3. C(i) Planar (ii) Yes geometrical isomerism (iii) Polar
  4. D(i) Non Planar (ii) No geometrical isomerism (iii) Not Polar

Correct answer

A. (i) Non-planar (ii) No geometrical isomerism (iii) Polar

Step-by-step solution

Hybridization of central carbon is sp and two of its unhybridized p -orbitals are involved in π - bonding. Also p - orbitals at an atom are orthogonal (at 90 ο angle), the two π - bonds at central carbon are also orthogonal. Let these p - orbitals, involved in π - bonding, at central carbon be p y and p z , then Hybridization at the terminal carbons are both sp 2 . The two p - orbitals involved in sp 2 hybridization are p x and p y at left terminal and p x and p z at right terminals. Therefore, the three s p 2 hybr

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