NTA Abhyas JEE Main2020ChemistryChemical Bonding and Molecular StructurePractice
Arrange the following in the correct order of Lewis acidity: BF 3 , BCl 3 , BBr 3 .
Options
- ABF 3 > BBr 3 > BCl 3
- BBF 3 > BCl 3 > BBr 3
- CBF 3 < BCl 3 < BBr 3
- DBBr 3 < BF 3 < BCl 3
Correct answer
C. BF 3 < BCl 3 < BBr 3
Step-by-step solution
In BF 3 , BCl 3 and BBr 3 each will shown p π - p π back bonding as follows. Extant of overlapping as the 2 p − 2 p > 2 p − 3 p > 2 p − 4 p difference between the size of p orbital increases the extent of overlapping decreases the availability of vacant orbital increases and the acidic character increases. Hence correct order of Lewis acidity represented by option (BF 3 < BCl 3 < BBr 3 ) .