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NTA Abhyas JEE Main2020ChemistryChemical Bonding and Molecular StructurePractice

The bond angles in NH 3 , NF 3 and NCl 3 are in the order :

Options

  1. ANCl 3 > NH 3 > NF 3
  2. BNH 3 > NCl 3 > NF 3
  3. CNF 3 > NH 3 > NCl 3
  4. DNF 3 > NCl 3 > NH 3

Correct answer

A. NCl 3 > NH 3 > NF 3

Step-by-step solution

Comparison of NH 3 and NF 3 : Since N is more electronegative than hydrogen, shared pair of electrons of the N - H bond spent more time with nitrogen ( closer to nitrogen) giving a greater bond pair repulsion. On the other hand fluorine is more electronegative than nitrogen, shared pair of electrons of N - F bond spent more times with fluorine ( closer to fluorine ) giving less bond pair repulsion as compared to N - H bond. Although bond pair bond pair repulsion in both cases are less than lone pair - bond repulsio

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