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When two compounds ACl 3 and DCl 3 of two elements A and D are mixed together a compound ADCl 6 is formed. Structural analysis showed that ADCl 6 is an ionic compound. Given that DCl 3 is trigonal planar and ACl 3 is trigonal pyramidal. If anion has see-saw shape then shape of cation formed is

Options

  1. ALinear
  2. BBent
  3. CPentagonal bipyramidal
  4. DTrigonal planar

Correct answer

A. Linear

Step-by-step solution

⇒ As DCl 3 is trigonal planar, hence, 'D' belongs to boron family. ⇒ As ACl 3 is trigonal pyramidal, hence, 'A' belongs to nitrogen family. ⇒ DCl 3 + ACl 3 → [DCl 2 ] + [ACl 4 ] – or [ACl 2 ] + [DCl 4 ] – If anionic part is [ACl 4 ] – which has Sea - saw structure then cationic part will be [DCl 2 ] + where hybridization of D will be 'sp' and hence, shape will be linear. ⇒ If anionic part is DCl 4 - i.e, it is of tetrahedral shape the cation part wi

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