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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

In the esterification C _ 2 H _ 5 OH (l) + C H _ 3 COOH (l) ⇌ C H _...

In the esterification C2H5OH{C}_{2}{H}_{5}OH\left(l\right) + C{H}_{3}COOH(l)⇌CH3COOC2H5(l)+H2O(l)\left(l\right) ⇌ C{H}_{3}COO{C}_{2}{H}_{5}\left(l\right) + {H}_{2}O\left(l\right) an equimolar mixture of alcohol and acid taken initially yields under equilibrium, the water with mole fraction = 0.333. The equilibrium constant is.In the esterification C _ 2 H _ 5 OH (l) + C H _ 3 COOH (l) ⇌ C H _ 3 COO C _ 2 H _ 5 (l) + H _ 2 O(l) an equimolar

Correct answer

4

Step-by-step solution

As alcohol and acid are equimolar so the initial concentration would also be same. Suppose the initial concentration is 'C'.
In the esterification C _ 2 H _ 5 OH (l) + C H _ 3 COOH (l) ⇌ C H _ 3 COO C _ 2 H _ 5 (l) + H _ 2 O(l) an equimolar
x(C−x)+(C−x)+x+x=0.33=13\dfrac{x}{\left(C - x\right) + \left(C - x\right) + x + x} = 0.33 = \dfrac{1}{3}
3x=2C3x = 2C
x=2C3x = \dfrac{2C}{3}
Kc=2C3×2C3(C−2C3)×(C−2C3)=4{K}_{c} = \dfrac{\dfrac{2C}{3} \times \dfrac{2C}{3}}{\left(C - \dfrac{2C}{3}\right) \times \left(C - \dfrac{2C}{3}\right)} = 4
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